If you're looking for anime similar to Precarious Woman Executive Miss Black General, you might like these titles.
There are two sides to every coin... light vs. dark, good vs. evil, love vs. hate. Sometimes the line between the two grows thin... and it's so, so easy to cross. So it's no surprise that Fudo Aikawa, A.K.A. Red Gelato of the Gelato Five and hero to all people, just may have happened to fall for the villainess and member of the shadow organization Gekko, Desumi Magahara! But when opposites like these attract, there's more than a few obstacles to their love...! What's a pair like this to do?
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Similar premise: a female villain falls in love with a superhero she's supposed to be fighting. LAWD is more action oriented, while Miss Black General relies more on situational/gag comedy. Both are humorous in their own way.
Mitsuo encountered Superman, an alien who is a part of a federation that tries to maintain peace in the galaxy. He then received a helmet (that also serves as a mask) that gives superhuman strength, a cape that enables the wearer to fly, and a badge that allows him to breathe underwater and communicate with his fellow comrades whom he met soon after he utilized these gifts. Superman made it clear to all Permans that their identity must be kept a secret or their brain will be destroyed should it ever be revealed and they are given a special doppelganger robot that can replace them while they are away to achieve this feat, although it is not entirely foolproof nor is it free from potential problems. These equipments then allowed them to be young Permans who try to maintain peace and help the people who are in need.
After dealing with the villains that infiltrated the school premises, the rescue training is resumed. But not all goes as planned, as there is a villain still hidden in the USJ.
Izuku looks back at the events that brought him to U.A. High School and on his path to becoming a hero.